The only thing that I can think of is to slather your armpits with Aquaphor or Vaseline before swimming.
If you’re using an underarm deodorant or anti-perspirant, you might NOT want to apply before swimming. There might be some kind of negative reaction between salt water and the underarm deodorant / anti-perspirant.
Do you have the same armpit irritation when swimming in a chlorinated swimming pool?
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